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Introduction

Chapter Concepts

Properties equilibrium phase diagram; excess Gibbs energy; excess chemical potential; excess enthalpy; excess entropy; excess volume; fugacity; mole fraction; pressure; temperature; thermodynamic activity
Keywords activity coefficient; excess Gibbs energy; introduction; mixture; nonelectrolyte; solution; vapor-liquid equilibrium
Main Subjects Introduction
Secondary Subjects Activity and activity coefficient; Concentration dependence of activity coefficients in binary systems; Consistency tests; Correction for real behavior of vapor phase; Correlation of experimental data; Dew and bubble point methods; Dynamic (circulation) methods; Excess Gibbs energy; Flow methods; Fugacity and fugacity coefficient; General references; General thermodynamic relations; Other methods; Principles and methods of measurement; Saturation (transpiration) methods; Sources of errors; Static methods; Test mixtures; Vapor-liquid equilibrium phase diagrams

Table of Contents:

  • Introduction
    • General thermodynamic relations
    • Fugacity and fugacity coefficient
    • Activity and activity coefficient
    • Excess Gibbs energy
    • Concentration dependence of activity coefficients in binary systems
    • Correction for real behavior of vapor phase
    • Vapor-liquid equilibrium phase diagrams
    • Principles and methods of measurement
      • Static methods
      • Dynamic (circulation) methods
      • Flow methods
      • Dew and bubble point methods
      • Saturation (transpiration) methods
      • Other methods
    • Sources of errors
    • Consistency tests
    • Correlation of experimental data
    • Test mixtures
    • General references

Source

Title

Introduction
In

Vapor-Liquid Equilibrium in Mixtures and Solutions
Author I. Wichterle, J. Linek, Z. Wagner, J.-C. Fontaine, K. Sosnkowska-Kehiaian, H. V. Kehiaian
Affiliation
Institute of Chemical Process Fundamentals, Academy of Sciences, Prague, Czech Republic; CNRS, Paris, France; University of Paris VII, Paris, France
Part of Landolt-Börnstein - Group IV Physical Chemistry
Numerical Data and Functional Relationships in Science and Technology
Volume

13A1: Binary Liquid Systems of Nonelectrolytes. Part 1
Edited by H.V. Kehiaian
Chapter-DOI 10.1007/978-3-540-49315-0_1
Book-DOI 10.1007/978-3-540-49315-0 (Volume in Bookshelf)

Cite as

RIS-Export Wichterle, I., Linek, J., Wagner, Z., Fontaine, J.-C., Sosnkowska-Kehiaian, K., Kehiaian, H. V.: Introduction. Kehiaian, H.V. (ed.). SpringerMaterials - The Landolt-Börnstein Database (http://www.springermaterials.com). DOI: 10.1007/978-3-540-49315-0_1

Abstract

Introduction in 'Vapor-Liquid Equilibrium in Mixtures and Solutions', part of 'Landolt-Börnstein - Group IV Physical Chemistry: Numerical Data and Functional Relationships in Science and Technology, Volume 13A1: Binary Liquid Systems of Nonelectrolytes. Part 1'.
This document is part of Subvolume A1 'Binary Liquid Systems of Nonelectrolytes. Part 1' of Volume 13 'Vapor-Liquid Equilibrium in Mixtures and Solutions' of Landolt-Börnstein - Group IV 'Physical Chemistry'. It provides the introduction and the general references. 1 Introduction 1.1 General thermodynamic relations 1.2 Fugacity and fugacity coefficient 1.3 Activity and activity coefficient 1.4 Excess Gibbs energy 1.5 Concentration dependence of activity coefficients in binary systems 1.6 Correction for real behavior of vapor phase 1.7 Vapor-liquid equilibrium phase diagrams 1.8 Principles and methods of measurement 1.9 Sources of errors 1.10 Consistency tests 1.11 Correlation of experimental data 1.12 Test mixtures 5 General references